{"id":11849,"date":"2018-07-25T21:28:29","date_gmt":"2018-07-26T04:28:29","guid":{"rendered":"http:\/\/cafe.foundation\/blog\/?p=11849"},"modified":"2018-07-25T21:28:29","modified_gmt":"2018-07-26T04:28:29","slug":"john-goodenoughs-counter-intuitive-battery","status":"publish","type":"post","link":"http:\/\/cafe.foundation\/blog\/john-goodenoughs-counter-intuitive-battery\/","title":{"rendered":"John Goodenough&#8217;s Counter-intuitive Battery"},"content":{"rendered":"<h4>A Long and Productive Life<\/h4>\n<p>On his 96<sup>th<\/sup> birthday today, John Goodenough and his research team\u2019s latest findings are the subject of much speculation.\u00a0 He, fellow scientist Maria Braga, and his research team have created a battery claimed to be three times as energy dense as existing lithium-ion contemporaries, but exhibiting the counterintuitive property of improving with repeated charging cycles.<\/p>\n<p>Goodenough\u2019s career began in 1943 (a year after your editor was born) with the award of his bachelor\u2019s degree in mathematics from Yale University, followed his master\u2019s and Ph.D. in physics from the University of Chicago in 1951 and 1952 respectively.\u00a0 He worked at MIT and in 1976, left to become head of Oxford University\u2019s Inorganic Chemistry Laboratory from 1976 to 1986.\u00a0 In 1986, he assumed the Virginia H. Cockrell Centennial Chair in Engineering at the University of Texas at Austin, at an age where most men are cashing in their 401k\u2019s.<\/p>\n<p><iframe loading=\"lazy\" title=\"John Goodenough: Taming the Explosive Nature of Lithium to Make a Better Battery\" width=\"500\" height=\"281\" src=\"https:\/\/www.youtube.com\/embed\/9u6pWOI4zPc?feature=oembed\" frameborder=\"0\" allow=\"accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share\" referrerpolicy=\"strict-origin-when-cross-origin\" allowfullscreen><\/iframe><\/p>\n<p><a href=\"https:\/\/www.texasmonthly.com\/energy\/all-charged-up-john-goodenough\/\"><em>Texas Monthly<\/em><\/a> comments on the counterintuitive nature of the man himself.\u00a0 \u201cAnd yet, he\u2019s a bit of an anomaly in the research world. For one, \u2018I use chemistry to answer physics questions,\u2019 he says. Also, he sees a connection between his scientific pursuits and his Christian faith: \u2018If you believe that there\u2019s a creator, you should show respect for that creator by respecting his creation. Scientists show respect for creation by studying our planet and how it works. They serve people with their discoveries.\u2019\u201d<\/p>\n<div id=\"attachment_12943\" style=\"width: 538px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-12943\" class=\"size-large wp-image-12943\" src=\"http:\/\/sustainableskies.org\/wp-content\/uploads\/2018\/07\/goodenough_john_2017_95th_pre-birthday_party8739-1-528x352.jpg\" alt=\"\" width=\"528\" height=\"352\" \/><p id=\"caption-attachment-12943\" class=\"wp-caption-text\">John Goodenough&#8217;s\u00a0 2017 95th pre-birthday party in the Maker Studio at the Cockrell School of Engineering &#8211; photo taken on June 30, 2017. His actual birthday is on July 25.\u00a0\u00a0Photo by Marsha Miller<\/p><\/div>\n<p><a href=\"https:\/\/news.utexas.edu\/2017\/07\/25\/happy-95th-birthday-john-goodenough\">The University of Texas writes of his accomplishments,<\/a> \u201cIn 1979, his discovery of the lithium-ion battery dramatically shaped the world of consumer electronics. These rechargeable batteries are now used by millions of people every day to power consumer electronics as diverse as cellphones, tablets, cameras and tools. You are probably holding one right now.\u201d<\/p>\n<p>Eric Schmidt, Executive Chairman &amp; former CEO of Google, and Elon Musk, head of a large electric car company, have both lauded Goodenough\u2019s work.<\/p>\n<h4><strong>The Paper<\/strong><\/h4>\n<p>\u201cNontraditional, Safe, High Voltage Rechargeable Cells of Long Cycle Life,\u201d published in the April 24, 2018 issue of the <em>Journal of the American Chemical Society<\/em>, hides a great deal of promise behind a humble title.\u00a0 Co-authors <a href=\"https:\/\/pubs.acs.org\/author\/Braga%2C+Maria+Helena\">Maria Helena Braga<\/a>, <a href=\"https:\/\/pubs.acs.org\/author\/M+Subramaniyam%2C+Chandrasekar\">Chandrasekar M Subramaniyam<\/a>, <a href=\"https:\/\/pubs.acs.org\/author\/Murchison%2C+Andrew+J\">Andrew J. Murchison<\/a>, and <a href=\"https:\/\/pubs.acs.org\/author\/Goodenough%2C+John+B\">John B. Goodenough<\/a> share honors for this potentially exciting revelation.\u00a0 (Cautionary note: other researchers seem to be expressing a great deal of skepticism about this research, although honoring Goodenough and Braga\u2019s demonstrated skills as researchers.)<\/p>\n<p><iframe loading=\"lazy\" title=\"The Glass Batteries That Are More Than Good Enough!\" width=\"500\" height=\"281\" src=\"https:\/\/www.youtube.com\/embed\/wl0I2vl6ul0?feature=oembed\" frameborder=\"0\" allow=\"accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share\" referrerpolicy=\"strict-origin-when-cross-origin\" allowfullscreen><\/iframe><\/p>\n<p>Why is it exciting?\u00a0 First, the battery has gone through over 23,000 cycles.\u00a0 Most researchers seem to announce results after a hundred or so cycles, avoiding the issue of how their cells will hold up long term.\u00a0 Second, the battery gains specific capacity (milliamp hours per gram) as the number of cycles increases.\u00a0 Normally, batteries lose storage capacity as they are used.\u00a0 Since the 23,000 cycles would allow a charge\/recharge cycle every day for 63 years, this is essentially a lifetime battery.\u00a0 Third, there is no cobalt, expensive and with the market cornered by China.\u00a0 It\u2019s replaced by more common, less expensive materials.\u00a0 Fourth, it\u2019s a solid-state battery, with no liquid electrolyte to ignite.\u00a0 Fifth, it charges in quick-time, much like a capacitor.<\/p>\n<div id=\"attachment_12945\" style=\"width: 510px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-12945\" class=\"size-full wp-image-12945\" src=\"http:\/\/sustainableskies.org\/wp-content\/uploads\/2018\/07\/Goodeenough-battery-cycle.gif\" alt=\"\" width=\"500\" height=\"404\" \/><p id=\"caption-attachment-12945\" class=\"wp-caption-text\">That controversial rise in capacity with an increasing number of cycles. Where will it end?<\/p><\/div>\n<p>The so-called \u201cglass battery\u201d has several areas of controversy,<a href=\"https:\/\/www.axios.com\/battery-pioneer-1528047409-d0515380-1881-4e96-891f-3763eaa84666.html\"> as listed an article in <em>Axios<\/em><\/a>.\u00a0 Its high &#8220;relative dielectric constant,&#8221; a measure of energy storage in an electrical field, is higher than any recorded for a material.\u00a0 <em>Axios<\/em> says the paper apparently does not make clear whether an unplugged battery of this type will hold its charge for any significant time, although parts of the JACS paper seem to address this.\u00a0 \u00a0The battery\u2019s ability to increase capacity through repeated charging elicits the most skepticism, expressed by six battery scientists contacted by <em>Axios<\/em>.<\/p>\n<div id=\"attachment_12944\" style=\"width: 538px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-12944\" class=\"size-large wp-image-12944\" src=\"http:\/\/sustainableskies.org\/wp-content\/uploads\/2018\/07\/maria-helena-braga-528x704.jpg\" alt=\"\" width=\"528\" height=\"704\" \/><p id=\"caption-attachment-12944\" class=\"wp-caption-text\">Researcher Maria Helena Braga works on the glass electrolyte for the new battery. Doped with lithium or sodium, the glass electrolyte allows the battery to be recharged within minutes instead of hours.<\/p><\/div>\n<p>Maria Braga responded to the criticism in a follow-up to the article.\u00a0 \u201cData is data and we have similar data from many different cells, in four different instruments, different labs, glove box. And at the end of the day, the LEDs are lit for days with a very small amount of active material after having cycled for more than 23,000 times.&#8221;\u00a0 (The \u201cglove box\u201d reference is not explained.)<\/p>\n<p>Goodenough\u2019s contributions are found in virtually every lithium battery today.\u00a0 Even though he\u2019s often mentioned as a potential Nobel Prize winner, his efforts have rarely given him substantial financial compensation.\u00a0 His determined outlook and happy disposition seem to be their own reward, though, and his research continues.\u00a0 He foresees his latest creations achieving commercial status in the next two years.\u00a0 Let\u2019s hope he\u2019s right.<\/p>\n<div id=\"facebook_like\"><iframe src=\"http:\/\/www.facebook.com\/plugins\/like.php?href=http%3A%2F%2Fcafe.foundation%2Fblog%2Fjohn-goodenoughs-counter-intuitive-battery%2F&amp;layout=standard&amp;show_faces=true&amp;width=500&amp;action=like&amp;font=segoe+ui&amp;colorscheme=light&amp;height=80\" scrolling=\"no\" frameborder=\"0\" style=\"border:none; overflow:hidden; width:500px; height:80px;\" allowTransparency=\"true\"><\/iframe><\/div>","protected":false},"excerpt":{"rendered":"<p>A Long and Productive Life On his 96th birthday today, John Goodenough and his research team\u2019s latest findings are the subject of much speculation.\u00a0 He, fellow scientist Maria Braga, and his research team have created a battery claimed to be three times as energy dense as existing lithium-ion contemporaries, but exhibiting the counterintuitive property of [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[6862,6660,14],"tags":[8707,8708,8709,1283,6726,7759,5068,7760,8710,8711,3015,8712,1138],"class_list":["post-11849","post","type-post","status-publish","format-standard","category-batteries","category-electric-aircraft-materials","category-sustainable_ga","tag-andrew-j-murchison","tag-axios","tag-chandrasekar-m-subramaniyam","tag-elon-musk","tag-eric-schmidt","tag-john-goodenough","tag-journal-of-the-american-chemical-society","tag-maria-helena-braga","tag-oxford-universitys-inorganic-chemistry-laboratory","tag-univerity-of-texas-at-austin","tag-university-of-chicago","tag-virginia-h-cockrell-centennial-chair-in-engineering","tag-yale-university"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.7 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>John Goodenough&#039;s Counter-intuitive Battery - CAFE Foundation Blog<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"http:\/\/cafe.foundation\/blog\/john-goodenoughs-counter-intuitive-battery\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"John Goodenough&#039;s Counter-intuitive Battery - CAFE Foundation Blog\" \/>\n<meta property=\"og:description\" content=\"A Long and Productive Life On his 96th birthday today, John Goodenough and his research team\u2019s latest findings are the subject of much speculation.\u00a0 He, fellow scientist Maria Braga, and his research team have created a battery claimed to be three times as energy dense as existing lithium-ion contemporaries, but exhibiting the counterintuitive property of [&hellip;]\" \/>\n<meta property=\"og:url\" content=\"http:\/\/cafe.foundation\/blog\/john-goodenoughs-counter-intuitive-battery\/\" \/>\n<meta property=\"og:site_name\" content=\"CAFE Foundation Blog\" \/>\n<meta property=\"article:published_time\" content=\"2018-07-26T04:28:29+00:00\" \/>\n<meta property=\"og:image\" content=\"http:\/\/sustainableskies.org\/wp-content\/uploads\/2018\/07\/goodenough_john_2017_95th_pre-birthday_party8739-1-528x352.jpg\" \/>\n<meta name=\"author\" content=\"Dean Sigler\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Dean Sigler\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"4 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"http:\\\/\\\/cafe.foundation\\\/blog\\\/john-goodenoughs-counter-intuitive-battery\\\/#article\",\"isPartOf\":{\"@id\":\"http:\\\/\\\/cafe.foundation\\\/blog\\\/john-goodenoughs-counter-intuitive-battery\\\/\"},\"author\":{\"name\":\"Dean Sigler\",\"@id\":\"http:\\\/\\\/cafe.foundation\\\/blog\\\/#\\\/schema\\\/person\\\/e9c06a89f78d39fc03473ec90f4902a7\"},\"headline\":\"John Goodenough&#8217;s Counter-intuitive Battery\",\"datePublished\":\"2018-07-26T04:28:29+00:00\",\"mainEntityOfPage\":{\"@id\":\"http:\\\/\\\/cafe.foundation\\\/blog\\\/john-goodenoughs-counter-intuitive-battery\\\/\"},\"wordCount\":870,\"commentCount\":0,\"image\":{\"@id\":\"http:\\\/\\\/cafe.foundation\\\/blog\\\/john-goodenoughs-counter-intuitive-battery\\\/#primaryimage\"},\"thumbnailUrl\":\"http:\\\/\\\/sustainableskies.org\\\/wp-content\\\/uploads\\\/2018\\\/07\\\/goodenough_john_2017_95th_pre-birthday_party8739-1-528x352.jpg\",\"keywords\":[\"Andrew J. 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