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<\/a>Cylinder within cylinder layout may obviate use of more conventional manufacturing methods<\/p><\/div>\n
The team\u2019s paper, \u201cHigh Energy-Density Solid Electrolyte-Based Liquid Li-S and Li-Se Batteries,\u201d published in the October 15 edition of Joule<\/em>, explains the new batteries should be capable of delivering energy densities of around 2,600 Watt-hours per kilogram for the lithium-sulfur chemistry and 1,160 Wh\/kg. for lithium-selenium.<\/em>\u00a0 \u00a0Currently, researchers have achieve 500 Wh\/kg, double the best Li packs today.\u00a0 This can be achieved at cost of $41 per kilowatt-hour for the Li-Se battery and $15 per kW-hr for the sulfur-based version.<\/p>\n The abstract for the paper reads: \u201cLithium-sulfur (Li-S) and Lithium-selenium (Li-Se) batteries are considered as promising candidates for next-generation battery technologies, as they have high energy density and low cost. However, due to the use of a solid Li-metal anode and a liquid organic electrolyte, the current Li-S and Li-Se batteries face several issues in terms of Coulombic efficiency and cycling stability, which seriously impeded their development. Here, we report solid-electrolyte-based liquid Li-S and Li-Se (SELL-S and SELL-Se in short) batteries. The batteries use a Li\u00a06.4La\u00a03Zr\u00a01.4Ta\u00a00.6O\u00a012\u00a0(LLZTO) ceramic tube as electrolyte and work at temperatures higher than the melting point of Li; thus, polysulfide or polyselenide shuttle effects and Li dendrite growth are effectively prevented, and high energy density, together with high stability, fast charge\/discharge capability, high Coulombic efficiency, and high energy efficiency, can be achieved. The SELL-S and SELL-Se batteries provide broader platforms for constructing high-energy, high-power, long-lifetime, and low-cost energy storage.\u201d<\/p>\n Differential transfer of materials during lithiation may contribute to high energy density<\/p><\/div>\n The combination of low cost and high output could be a real winner in the commercial market, and would open the way for large-scale energy storage for wind and solar power.\u00a0 Now only at the laboratory stage, the promising technology makes one hope this can be quickly scaled up and adopted by significant users.<\/p>\n Batteries in which lithium is a major factor may become costly to produce in the United States, which is ninth in the world\u2019s use of the metal for batteries.\u00a0 Spreading that cost among other, cheaper materials might help.<\/p>\n According to Fortune magazine, a ton of lithium (battery grade) would bring $20,000 in 2016<\/a>.\u00a0 Sulfur tends to fluctuate in price<\/a>, ranging from $30 per ton to $480 for medical grade material. Selenium would not be a cost saver<\/a>, averaging around $48,000 per ton in 2016.\u00a0 Carbon black is a bargain at $93 per ton<\/a> despite recent price increases.\u00a0 Lanthanum, a rare-earth mineral, can be had for $1,000 to $1,200 per ton, although laboratory grades sell for much more.\u00a0 High quality Zirconium oxide can sell for anywhere from $1.5 to $70 per kilogram.\u00a0 Most costly, tantalum<\/a>, reputed to be a conflict metal sold for !51,800 per ton in 2018.<\/p>\n It must take minute amounts of certain of these materials to enable low costs for SELL-S and SELL-Se batteries.\u00a0 We hope researchers can find ways manufacture such cells on an equally economic basis.<\/p>\n<\/a>