{"id":8485,"date":"2013-12-02T13:53:39","date_gmt":"2013-12-02T20:53:39","guid":{"rendered":"http:\/\/cafe.foundation\/blog\/?p=8485"},"modified":"2013-12-02T13:53:39","modified_gmt":"2013-12-02T20:53:39","slug":"converging-paths-head-toward-better-supercapacitors","status":"publish","type":"post","link":"http:\/\/cafe.foundation\/blog\/converging-paths-head-toward-better-supercapacitors\/","title":{"rendered":"Converging Paths Head toward Better Supercapacitors"},"content":{"rendered":"<p>Two different lines of research in Korea and Australia seem to be heading toward practical supercapacitors with energy densities approaching the lower end of battery technology while offering better charging efficiency and extended lifetimes.<\/p>\n<p>Santhakumar Kannappan, a researcher at the Gwangju Institute of Science and Technology in Korea has led a team who reduced graphene oxide particles with hydrazine in water, then agitated the slurry with ultrasound.\u00a0 This produces a \u201chighly porous form of graphene that has a huge internal surface area,\u201d equivalent to a basketball court for every gram.\u00a0 They pack the resulting powder into a coin-shaped cell, dry it at 140\u00b0 C and a pressure of 300 kilograms per centimeter (4,267 pounds per square inch) for five hours.<\/p>\n<div id=\"attachment_8486\" style=\"width: 410px\" class=\"wp-caption aligncenter\"><a href=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphenecork-1.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-8486\" class=\"size-full wp-image-8486\" alt=\"Graphene cork made by Guanxii University -  lighter than air, able to support over 50,000 times their own weight, and good conductors of electricity\" src=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphenecork-1.jpg\" width=\"400\" height=\"399\" srcset=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphenecork-1.jpg 400w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphenecork-1-150x150.jpg 150w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphenecork-1-300x300.jpg 300w\" sizes=\"auto, (max-width: 400px) 100vw, 400px\" \/><\/a><p id=\"caption-attachment-8486\" class=\"wp-caption-text\">Graphene cork made last year by Monash University &#8211; lighter than air, able to support over 50,000 times its own weight, and a good conductor of electricity &#8211; because of its enormous internal surface area<\/p><\/div>\n<p>Electrodes made this way and saturated in EBIMF 1 M electrolyte have a specific capacitance of 150 Farads per gram, an energy density of 64 Watt-hours per kilogram and a current density of 5 Amps per gram.<\/p>\n<p><a href=\"http:\/\/www.technologyreview.com\/view\/521651\/graphene-supercapacitors-ready-for-electric-vehicle-energy-storage-say-korean-engineers\/\">MIT\u2019s Technology Review<\/a> says, \u201cThat\u2019s almost comparable with lithium-ion batteries, which have an energy density of between 100 and 200 watt-hours per kilogram.\u201d\u00a0 To this editor, that seems more like one-third of current best performers in the lithium battery market, although wildly more energy dense than most supercapacitors.<\/p>\n<p>Of greater interest may be their longevity, with 10,000 charging\/discharge repetitions \u201cwithout a significant reduction in capacitance\u2026 the highest so far reported in the literature,\u201d according to Gwangiu researchers.\u00a0 Their supercapacitor pack also charges in a mere 16 seconds, beating the need to go shopping for long hours while one\u2019s EV refreshes itself.<\/p>\n<p>Kannappan and his team think that, \u201csupercapacitor energy storage devices \u2026 can be scaled up for manufacturing in the near future for electric vehicle applications.\u201d<\/p>\n<p>Their research can be seen in greater depth in their <a href=\"arxiv.org\/abs\/1311.1548\">paper<\/a>, \u201cGraphene based Supercapacitors with Improved Specific Capacitance and Fast Charging Time at High Current Density.\u201d<\/p>\n<div id=\"attachment_8488\" style=\"width: 538px\" class=\"wp-caption aligncenter\"><a href=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-paper-640x333.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-8488\" class=\"size-large wp-image-8488\" alt=\"Capillary-like action pulls electrolyte into graphene paper\" src=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-paper-640x333-528x274.jpg\" width=\"528\" height=\"274\" srcset=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-paper-640x333-528x274.jpg 528w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-paper-640x333-300x156.jpg 300w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-paper-640x333.jpg 640w\" sizes=\"auto, (max-width: 528px) 100vw, 528px\" \/><\/a><p id=\"caption-attachment-8488\" class=\"wp-caption-text\">Capillary-like action pulls electrolyte into compressed graphene paper in Monash University process<\/p><\/div>\n<p>The manufacturing side of commercializing these breakthroughs may find a home at Monash University in Australia.\u00a0 There, materials engineers make similar performance claims for their supercapacitor materials that are <a href=\"http:\/\/www.extremetech.com\/computing\/163071-graphene-supercapacitors-created-with-traditional-paper-making-process-rivals-lead-acid-battery-capacity\">rolled out in a fashion like that of traditional paper making<\/a>.<\/p>\n<p>Dan Li, head researcher for this effort, says his team\u2019s says his team\u2019s supercapacitors are about 10 times more energy dense than commercial devices, noting energy densities similar to lead-acid batteries.\u00a0 They even use a similar starting point, mixing graphite oxide that\u2019s been reduced to low-grade graphene flakes in a solution of hydrazine and ammonia.\u00a0 \u201cAs the mixture dries, the volatile solvent evaporates, causing capillary action to suck the graphene flakes together, with the electrolyte wedged between each of the flakes. Eventually the engineers are left with something that resembles a black sheet of paper \u2014 millions of layers of graphene, with oodles of charge-carrying electrolyte locked in.\u201d<\/p>\n<div id=\"attachment_8489\" style=\"width: 538px\" class=\"wp-caption aligncenter\"><a href=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-supercapacitor.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-8489\" class=\"size-large wp-image-8489\" alt=\"Artist's conception of graphene supercapacitor charging - in only 16 seconds, rather than hours required for batteries\" src=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-supercapacitor-528x350.jpg\" width=\"528\" height=\"350\" srcset=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-supercapacitor-528x350.jpg 528w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-supercapacitor-300x199.jpg 300w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2013\/12\/graphene-supercapacitor.jpg 628w\" sizes=\"auto, (max-width: 528px) 100vw, 528px\" \/><\/a><p id=\"caption-attachment-8489\" class=\"wp-caption-text\">Artist&#8217;s conception of graphene supercapacitor charging &#8211; in only 16 seconds, rather than hours required for batteries<\/p><\/div>\n<p>They end up with a paper-like creation that has a volumetric energy density of almost 60 watt-hours per liter, or about what a good lead-acid battery manages.\u00a0 Li claims higher potential cycle life, though, citing 90-percent capacitance retention after 50,000 charge\/discharge cycles.\u00a0 The paper holds 90-percent of its charge after 300 hours.<\/p>\n<p>Both research projects end up with similar outcomes in different formats, and the \u201csolution-based chemical reduction of graphite oxide\u201d common to both may well be a way to commercialize graphene.<\/p>\n<p>Monash\u2019s research is revealed in the <a href=\"http:\/\/www.sciencemag.org\/content\/341\/6145\/534\">paper<\/a>, \u201cLiquid-Mediated Dense Integration of Graphene Materials for Compact Capacitive Energy Storage,\u201d in the August 2013 journal Science.<\/p>\n<p>With supercapacitors well behind lithium batteries at this point, these two breakthroughs have brought supercapacitors to performance levels well beyond anything previously seen.\u00a0 The perfect combination of battery and supercapacitor technology may yet bring us a practical and economical means of energy storage.<\/p>\n<div id=\"facebook_like\"><iframe src=\"http:\/\/www.facebook.com\/plugins\/like.php?href=http%3A%2F%2Fcafe.foundation%2Fblog%2Fconverging-paths-head-toward-better-supercapacitors%2F&amp;layout=standard&amp;show_faces=true&amp;width=500&amp;action=like&amp;font=segoe+ui&amp;colorscheme=light&amp;height=80\" scrolling=\"no\" frameborder=\"0\" style=\"border:none; overflow:hidden; width:500px; height:80px;\" allowTransparency=\"true\"><\/iframe><\/div>","protected":false},"excerpt":{"rendered":"<p>Two different lines of research in Korea and Australia seem to be heading toward practical supercapacitors with energy densities approaching the lower end of battery technology while offering better charging efficiency and extended lifetimes. Santhakumar Kannappan, a researcher at the Gwangju Institute of Science and Technology in Korea has led a team who reduced graphene [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[15,14],"tags":[1057,4548,4549,4550,3202,4541,4544,4543,4546,4545,4542,1812,4547],"class_list":["post-8485","post","type-post","status-publish","format-standard","category-electric_powerplants","category-sustainable_ga","tag-australia","tag-dan-li","tag-ebimf-1-m-electrolyte","tag-graphene-based-supercapacitors","tag-graphene-sheets","tag-gwangju-institute-of-science-and-technology","tag-hydrazine","tag-mit-technology-review","tag-monash-university","tag-paper-making","tag-santhakumar-kannappan","tag-science","tag-south-korea"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.7 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Converging Paths Head toward Better Supercapacitors - CAFE Foundation Blog<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"http:\/\/cafe.foundation\/blog\/converging-paths-head-toward-better-supercapacitors\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Converging Paths Head toward Better Supercapacitors - CAFE Foundation Blog\" \/>\n<meta property=\"og:description\" content=\"Two different lines of research in Korea and Australia seem to be heading toward practical supercapacitors with energy densities approaching the lower end of battery technology while offering better charging efficiency and extended lifetimes. 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