{"id":8942,"date":"2014-05-26T08:50:14","date_gmt":"2014-05-26T15:50:14","guid":{"rendered":"http:\/\/cafe.foundation\/blog\/?p=8942"},"modified":"2014-05-26T08:50:14","modified_gmt":"2014-05-26T15:50:14","slug":"three-battery-technologies-great-potential","status":"publish","type":"post","link":"http:\/\/cafe.foundation\/blog\/three-battery-technologies-great-potential\/","title":{"rendered":"Three Battery Technologies with Great Potential"},"content":{"rendered":"<p><span style=\"line-height: 1.5em;\">It\u2019s a good week when at least three battery developments show promise for electric vehicle use in the near future.\u00a0 One advanced lithium-ion battery from France, a dual-carbon battery from Japan, and a supercapacitor that one can wrap around one\u2019s finger comprise the trio.<\/span><\/p>\n<p><b>French Lithium-Tin Dioxide<\/b><\/p>\n<p><b><\/b>\u201cSynthesizing nanoparticles of tin dioxide (SnO2) in the pores of a carbonaceous material,\u201d researchers at the <a href=\"http:\/\/www.icgm.fr\/?lang=en\">Institute of Materials Science of Mulhouse and Charles Gerhardt Institute of Montpellier<\/a>, part of an electrochemical energy storage consortium called RS2E, have found the material to have \u201cremarkable properties.\u201d\u00a0 Their work is the subject of a patent and published in the journal,\u00a0<i><a title=\"Confined SnO2 Ultrasmall Particles in Micro \/ Mesoporous Carbon as an Extremely Long Cycle Life Anode Material for Li-Ion Batteries\" href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aenm.201400025\/abstract\" target=\"_blank\">Advanced Energy Materials<\/a><\/i>.<\/p>\n<div id=\"attachment_8943\" style=\"width: 538px\" class=\"wp-caption aligncenter\"><a href=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Prius_batterie_lithium-ion.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-8943\" class=\"size-large wp-image-8943 \" alt=\"RS2E battery in the trunk of a Prius\" src=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Prius_batterie_lithium-ion-528x350.jpg\" width=\"528\" height=\"350\" srcset=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Prius_batterie_lithium-ion-528x350.jpg 528w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Prius_batterie_lithium-ion-300x198.jpg 300w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Prius_batterie_lithium-ion.jpg 1024w\" sizes=\"auto, (max-width: 528px) 100vw, 528px\" \/><\/a><p id=\"caption-attachment-8943\" class=\"wp-caption-text\">Lithium-ion battery in a Toyota Prius. With nanoparticles tin dioxide encompassed within a carbonaceous material, researchers were able to improve the performance of a lithium-ion battery.<\/p><\/div>\n<p>Researchers, hoping to obtain better performance that that achieved with carbon electrodes, tested combinations of nickel (Ni),\u00a0\u00a0iron\u00a0\u00a0(Fe), cobalt (Co), and other materials before hitting on tin dioxide as a material of choice.\u00a0 All have (theretically) far greater electrochemical storage capacity than graphite, but expand and contract during charging and discharging of the battery, often loosing particles which interfere with ion flow.<\/p>\n<p>The RS2E researchers found that confining two-nanometer-sized particles of tin dioxide in the interconnected pores of a carbon matrix helped improve battery performance with no irritating particle shedding.\u00a0 Researchers used \u201ccarbonaceous precursors respectful of the environment,\u201d which were then reduced and infused into the pores of the carbon.<\/p>\n<p>This homogeneous distribution of tin dioxide within the carbon was \u201ccontrolled and adjusted to absorb changes in volume of the particles during lithiation (battery charging) and reduce particle agglomeration (dendrites).\u201d\u00a0During testing, researchers noted higher output and excellent retention of charactertistics during extended cycling. (443 milliamp-hours per gram after 2,000 cycles, against 370 for the\u00a0graphite\u00a0\u00a0used in commercial batteries) and a near 100-percent efficiency.<\/p>\n<div id=\"attachment_8944\" style=\"width: 460px\" class=\"wp-caption aligncenter\"><a href=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Battery-chart.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-8944\" class=\"size-full wp-image-8944\" alt=\"Performance over extended Life Cycle shows promise of new battery technology\" src=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Battery-chart.jpg\" width=\"450\" height=\"322\" srcset=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Battery-chart.jpg 450w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/RS2E-Battery-chart-300x214.jpg 300w\" sizes=\"auto, (max-width: 450px) 100vw, 450px\" \/><\/a><p id=\"caption-attachment-8944\" class=\"wp-caption-text\">Performance over extended Life Cycle shows promise of new battery technology. \u00a0Confined tin dioxide (blue line) shows superior life cycle performance over unconfined electrode (red line).<\/p><\/div>\n<p><strong><span style=\"font-size: 1.17em; line-height: 1.5em;\">Japanese Dual-Carbon Battery<\/span><\/strong><\/p>\n<p><a href=\"http:\/\/powerjapanplus.com\/battery\/index.html\">The Ryden dual-carbon battery<\/a> \u201coffers energy density comparable to a lithium ion battery, but over a much longer functional lifetime with drastically improved safety and cradle-to-cradle sustainability,\u201d according to its makers.\u00a0 \u00a0Unlike most batteries that use different materials for anode and cathode, both are made of carbon in the Ryden cell.<\/p>\n<p>Because the materials in this battery are common and inexpensive, Dou Kani, CEO of Power Japan Plus, says, \u201cThe Ryden dual-carbon battery is the energy storage breakthrough needed to bring green technology like electric vehicles to mass market.\u201d\u00a0 Ryden thinks this will achieve their goals of performance, cost, reliability, safety and sustainability.<\/p>\n<p><iframe loading=\"lazy\" title=\"Power Japan Plus - Balancing the Energy Storage Equation\" width=\"500\" height=\"281\" src=\"https:\/\/www.youtube.com\/embed\/OJwZ9uEpJOo?start=21&#038;feature=oembed\" frameborder=\"0\" allow=\"accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share\" referrerpolicy=\"strict-origin-when-cross-origin\" allowfullscreen><\/iframe><\/p>\n<p>Most attractive, Ryden claims their cells are \u201cenergy dense,\u201d (although they avoid stating how dense), but they do say that their batteries can be charged 20 times faster than lithium ion batteries.\u00a0 The batteries also operate \u201cabove four Volts.\u201d\u00a0 Most lithium batteries run at or near 3.7 Volts.<\/p>\n<p>Because the battery can be manufactured on existing production lines, and has only carbon as an active material, prices can be kept low.\u00a0 Carbon is the fourth most abundant element in the universe after hydrogen, helium and oxygen, so there\u2019s little likelihood of a shortage any time soon, and no price spikes that occur with rare earth minerals.<\/p>\n<p>Ryden claims over 3,000 charge\/discharge cycles, enough to take your Tesla 900,000 miles (given equivalent energy density to today\u2019s batteries), or to fly 3,000 hours.\u00a0 Since the average lightplane logs 80 hours per year, these batteries would give over 37 years of service. \u00a0They\u2019d last a lifetime in a motorglider.<\/p>\n<p>Ryden claims theirs is \u201cthe safest high performance battery chemistry ever developed.\u201d\u00a0 Eliminating the \u201cunstable active material\u201d used in other batteries reduces fire and explosion hazards, and \u201cminimum thermal change during operation\u201d reduces the possibility of a thermal runaway.\u00a0 The battery can be charged and discharged 100 percent with no damage.<\/p>\n<p>The battery is 100-percent recyclable, and Power Japan Plus is testing the \u201cRyden battery with \u00a0its organic Carbon Complex material, working towards the goal of producing the battery with all organic carbon in the future.\u201d\u00a0Carbon Complex is made by precise reduction of organic cotton in a proprietary process.<\/p>\n<p>The company will begin making 18650 Ryden cells later this year in Okinawa, Japan, and will license the technology to others for larger demand industries.<\/p>\n<p>The press release concludes, \u201cCurrent advanced batteries have made great improvement on performance, but have done so by compromising on cost, reliability and safety,\u201d said Dr. Kaname Takeya, CTO of Power Japan Plus. \u201cThe Ryden dual carbon battery balances this equation, excelling in each category.\u201d\u00a0Let us hope the energy density is up to that claim.<\/p>\n<p><b>Thin film Flexibility with no Lithium <\/b><\/p>\n<p>James Tour, a chemist at Rice University and his colleagues have developed thin-film, flexible material with nanoporous nickel-fluoride electrodes layered around a solid electrolyte to deliver battery-like supercapacitor performance.\u00a0 It has no lithium, so may be safer than \u201cconventional\u201d batteries.\u00a0 The researchers\u2019 work is the the\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja501247f\">Journal of the American Chemical Society<\/a>.<\/p>\n<p>Reputedly combining the best aspects of batteries and supercapacitors, the electrochemical device is about a hundredth of an inch thick, \u201cbut can be scaled up for devices either by increasing the size or adding layers,\u201d according to Rice postdoctoral researcher Yang Yang, co-lead author of the paper with graduate student Gedeng Ruan.<\/p>\n<p>\u201cStandard manufacturing techniques\u201d will enable production of even thinner devices, according to the researchers.\u00a0 Tests showed that the test square-inch device held 76 percent of its capacity over 10,000 charge-discharge cycles and 1,000 bending cycles.\u00a0 Their new material is flexible like graphene, carbon nanotubes and conducting polymers, and has the electrical storage capacity found in inorganic metal compounds, which are not known for their flexibility.<\/p>\n<div id=\"attachment_8946\" style=\"width: 538px\" class=\"wp-caption aligncenter\"><a href=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/rice_FLEX-4-web.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-8946\" class=\"size-large wp-image-8946\" alt=\"Rice scientist claim an energy density of 384 Wh kg\u20131, and power density of 112 kW kg\u20131 for their flexible material\" src=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/rice_FLEX-4-web-528x150.jpg\" width=\"528\" height=\"150\" srcset=\"http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/rice_FLEX-4-web-528x150.jpg 528w, http:\/\/cafe.foundation\/blog\/wp-content\/uploads\/2014\/05\/rice_FLEX-4-web-300x85.jpg 300w\" sizes=\"auto, (max-width: 528px) 100vw, 528px\" \/><\/a><p id=\"caption-attachment-8946\" class=\"wp-caption-text\">Rice scientist claim an energy density of 384 Wh kg\u20131, and power density of 112 kW kg\u20131 for their flexible material<\/p><\/div>\n<p>\u201cCompared with a lithium-ion device, the structure is quite simple and safe,\u201d Yang said. \u201cIt behaves like a battery but the structure is that of a supercapacitor. If we use it as a supercapacitor, we can charge quickly at a high current rate and discharge it in a very short time. But for other applications, we find we can set it up to charge more slowly and to discharge slowly like a battery.\u201d<\/p>\n<p>Depositing a nickel layer on a backing, researchers \u201cetched it to create 5-nanometer pores within the 900-nanometer-thick nickel fluoride layer, giving it a high surface area for storage. Once they removed the backing, they sandwiched the electrodes around an electrolyte of potassium hydroxide in polyvinyl alcohol. Testing found no degradation of the pore structure even after 10,000 charge\/recharge cycles. The researchers also found no significant degradation to the electrode-electrolyte interface.\u201d<\/p>\n<p>\u201cThe numbers are exceedingly high in the power that it can deliver, and it\u2019s a very simple method to make high-powered systems,\u201d Tour said, adding that the technique shows promise for the manufacture of other 3-D nanoporous materials. \u201cWe\u2019re already talking with companies interested in commercializing this.\u201d<\/p>\n<p>Rice graduate student Changsheng Xiang and postdoctoral researcher Gunuk Wang are co-authors of the paper.<\/p>\n<p>&nbsp;<\/p>\n<div id=\"facebook_like\"><iframe src=\"http:\/\/www.facebook.com\/plugins\/like.php?href=http%3A%2F%2Fcafe.foundation%2Fblog%2Fthree-battery-technologies-great-potential%2F&amp;layout=standard&amp;show_faces=true&amp;width=500&amp;action=like&amp;font=segoe+ui&amp;colorscheme=light&amp;height=80\" scrolling=\"no\" frameborder=\"0\" style=\"border:none; overflow:hidden; width:500px; height:80px;\" allowTransparency=\"true\"><\/iframe><\/div>","protected":false},"excerpt":{"rendered":"<p>It\u2019s a good week when at least three battery developments show promise for electric vehicle use in the near future.\u00a0 One advanced lithium-ion battery from France, a dual-carbon battery from Japan, and a supercapacitor that one can wrap around one\u2019s finger comprise the trio. French Lithium-Tin Dioxide \u201cSynthesizing nanoparticles of tin dioxide (SnO2) in the [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[15,14],"tags":[1331,3868,5085,3869,5091,5089,5086,5068,5083,5088,779,5084,5087,5082,5090],"class_list":["post-8942","post","type-post","status-publish","format-standard","category-electric_powerplants","category-sustainable_ga","tag-advanced-energy-materials","tag-changsheng-xiang","tag-dou-kani","tag-gedeng-ruan","tag-gunuk-wang","tag-james-tour","tag-japan-power-plus","tag-journal-of-the-american-chemical-society","tag-materials-science-of-mulhouse-and-charles-gerhardt-institute-of-montpellier","tag-organic-carbon-complex-material","tag-rice-university","tag-rs2e","tag-ryden-battery","tag-tin-dioxide-sno2","tag-yang-yang"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.7 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Three Battery Technologies with Great Potential - CAFE Foundation Blog<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"http:\/\/cafe.foundation\/blog\/three-battery-technologies-great-potential\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Three Battery Technologies with Great Potential - CAFE Foundation Blog\" \/>\n<meta property=\"og:description\" content=\"It\u2019s a good week when at least three battery developments show promise for electric vehicle use in the near future.\u00a0 One advanced lithium-ion battery from France, a dual-carbon battery from Japan, and a supercapacitor that one can wrap around one\u2019s finger comprise the trio. 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